12 Class Chapter 15- Polymers

Polymer & Polymerization

Condensation Polymer: Nylon-6-6, Terylene.
Addition Polymer: Polythene, Neoprene.

Polymer Classification

Polymer Classification on the basis of Source:

1.    Natural Polymer: Protein, Cellulose, Rubber.
2.    Semi-synthetic Polymer: Cellulose Derivatives as cellulose acetate (Rayon), Cellulose Nitrate.
3.    Synthetic Polymer: Plastic (Polyethene), Synthetic Fibers (Nylon 6-6), Buna-S.

Polymer Classification on the basis of Structure:

1.    Linear Polymer: High Density Polythene, Polyvinyl Chloride.
2.    Branched Chain Polymer: Low Density Polythene.
3.     Cross Linked or Network Polymer: Bakelite, Melamine.

Polymer Classification on the basis of Molecular Forces:

1.    Elastomers: Weak intermolecular forces. eg.- Natural Rubber, Synthetic Rubber.
2.    Fibers: Strong intermolecular forces. eg.- Polyamides (Nylon6-6), Polyesters (Terylene).
3.    Thermoplastic: Polythene, Polystyrene.
4.    Thermosetting: Bakelite, Urea Formaldehyde Resins.

Lower Density Polyethene (L.D.P.): prepared at 1000-2000 atm pressure, 350-570 Kelvin Temperature and O2 peroxide inhibitor.

Higher Density Polyethene (H.D.P.): prepared at 6-7 atm pressure, 333-343 Kelvin Temperature and Zieglar Natta Catalyst.



Polymers
Monomers
Monomer Formula
Use
1.    Teflon
Tetrafluroethene
CF2=CF2
Oil seals, Gasket
2.    Polyacrylonitrile
Acrylonitrile

Commercial Fibers
3.    Terylene or Decron
Ethylene Glycol
Teryphthalic Acid
HOCH2-CH2OH


Commercial Fibers
4.    Nylon 6,6

And

5.    Nylon 6
Hexamethylene-diamine
Adipic Acid
Caprolactum
NH2(CH2)6NH2

HOOC(CH2)4COOH

Making Sheets, bristles of brushes, textile industry, tyre cords, fabrics, ropes etc.
6.    Phenol Formaldehyde Polymer
i.                   Novolac
Phenol + Formaldehyde
HCHO
Used in paints
ii.                 Bakelite
Phenol + Formaldehyde

HCHO
Comb, Electric switches
7.    Malamine Formaldehyde Polymer
Malamine + Formaldehyde

 HCHO
Unbreakable crockery
8.    Buna S
1,3-Butadiene + Styrene
CH2=CH-CH=CH2

Auto tyres, cables insulation, floor tiles


Plastics are synthetic or semi-synthetic materials made from polymers, which are long chains of molecules. They’re versatile, durable, and widely used in everything from packaging to car parts. The type of plastic depends on its chemical composition, properties, and intended use. Most plastics are categorized by a resin identification code (1 to 7), which you’ll often see on packaging, though these codes are more about recycling guidance than a strict classification.

Here’s a breakdown of the main types based on those codes:

  1. PET (Polyethylene Terephthalate, #1)
    • Used for: Soda bottles, water bottles, food packaging.
    • Properties: Clear, strong, lightweight, recyclable.
    • Example: Your typical single-use water bottle.
  2. HDPE (High-Density Polyethylene, #2)
    • Used for: Milk jugs, detergent bottles, toys.
    • Properties: Tough, resistant to chemicals, recyclable.
    • Example: The sturdy bottle your laundry detergent comes in.
  3. PVC (Polyvinyl Chloride, #3)
    • Used for: Pipes, window frames, vinyl flooring, some packaging.
    • Properties: Rigid or flexible (when plasticizers are added), weather-resistant.
    • Example: The plumbing pipes under your sink.
  4. LDPE (Low-Density Polyethylene, #4)
    • Used for: Plastic bags, shrink wrap, squeeze bottles.
    • Properties: Flexible, lightweight, less rigid than HDPE.
    • Example: Grocery bags that stretch easily.
  5. PP (Polypropylene, #5)
    • Used for: Yogurt containers, bottle caps, straws, car parts.
    • Properties: Heat-resistant, tough, recyclable.
    • Example: The lid on your takeout container.
  6. PS (Polystyrene, #6)
    • Used for: Foam cups, takeout containers, plastic cutlery.
    • Properties: Lightweight, brittle, can be foamed (like Styrofoam).
    • Example: The white foam box your burger came in.
  7. Miscellaneous (#7)
    • Used for: Miscellaneous plastics like polycarbonate (old baby bottles), nylon, or bioplastics.
    • Properties: Varies widely; not always recyclable.
    • Example: Some reusable water bottles or specialty containers.

Beyond these, plastics can also be classified by broader categories:

  • Thermoplastics: Soften when heated, can be reshaped (e.g., PET, HDPE, PP).
  • Thermosets: Harden permanently after heating, can’t be remolded (e.g., epoxy, phenolic resins).
  • Elastomers: Stretchy plastics like rubber (e.g., silicone, polyurethane).
  • Bioplastics: Made from renewable sources like corn starch (e.g., PLA), though not always biodegradable.

Each type has trade-offs. For instance, PET is great for clarity but not heat resistance, while PP can handle hot liquids but isn’t always crystal-clear. Recycling rates vary—HDPE and PET are more commonly recycled than PVC or PS due to infrastructure and demand. If you like 👍 then share with your friends and help us in spreading Science education…❤️🚀⚛️📚



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